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5.10 Water quality and material selection

Key idea: Bad water kills heat exchangers faster than anything else, so match materials and treatment to the site water.

Indian water ranges from soft rainwater to borewell water with TDS above 1,500 mg/L. Hardness (calcium and magnesium) forms scale on hot surfaces. Scale is a thermal blanket: a 1 mm layer can cut heat transfer noticeably and raise condensing pressure.

Key terms:

  • TDS (total dissolved solids): all dissolved salts, mg/L (ppm).
  • Hardness: calcium + magnesium, expressed as mg/L CaCO₃.
  • Chlorides: attack stainless steel (pitting), especially when hot.
  • pH: acidity; below about 6.5 corrodes copper, above about 9 encourages scale.

Typical guide values for water passing through a brazed plate or coaxial condenser (check manufacturer):

Parameter Typical acceptable Comment
pH 7.0–9.0
Total hardness < 150–200 mg/L as CaCO₃ Soften above this
TDS < 500 mg/L (preferred), up to ~1,000 with care
Chlorides < 100–200 mg/L for SS304 SS316 or titanium above
Free chlorine < 0.5–1 mg/L Pools need care
Iron < 0.2 mg/L Fouling

Material selection:

Water type Condenser material
Soft / RO municipal Copper-brazed SS316 plate or copper coaxial
Hard borewell Indirect loop + softener; SS316 PHE on user side
Swimming pool (chlorinated) Titanium coil
Sea / brackish water Titanium
Process with ammonia contact Nickel-brazed or fully welded SS (no copper)
Choose materials from a water test
Choose materials from a water test

Worked example — scale penalty

A unit in Jaipur on borewell water (hardness 450 mg/L) builds scale. Condensing temperature rises 4 K. Rule of thumb: COP falls roughly 2–3 % per K of extra lift (typical). COP drops from 3.5 to about 3.5 × (1 − 0.025 × 4) = 3.15. On 200 kWh heat/day: electricity rises from 57.1 to 63.5 kWh/day = 6.4 kWh × ₹9 = ₹58/day ≈ ₹21,000/year, before the cost of a failed condenser.

Remember

  • Test the water before selecting: pH, hardness, TDS, chlorides, iron.
  • Pools and sea water need titanium.
  • High hardness → softener and/or indirect loop.
  • Plan CIP (clean-in-place) connections on PHEs.
Field tip: Carry a TDS pen and a hardness strip kit to every site survey.

Bad water kills heat exchangers faster than anything else, so match materials and treatment to the site water.

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